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Francoise-Athenais de Rochechouart de Mortemart was born October 5, 1641 at the Chateau of Lussac-les Chateaux in the Poitou-Charentes region of France to parents of two of the oldest noble families, Gabriel de Rochechouart, Duke of Mortemart, and Diane de Grandseigne. From them she inherited a noble name, a great deal of wit, beauty, and not a great deal of money. But they had contacts at Court, and she spent her childhood moving with her mother between the family estates and the Court at the Louvre. At 12, she began her formal education at the Convent of St. Marie at Saintes, where her older sisters were also educated. At age 20, she became a maid-of-honor to the King's sister-in-law, Princess Henrietta-Anne (sister of Charles II of England), and later was appointed lady-in-waiting to the King's new Spanish wife Marie-Theresa. She was in position to find her destiny.
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By 1666, this had all paid off, and she was mistress to the King. She neatly replaced his current love, Louise de Valliere, who had just given birth to Louis's son. Athenais herself had 7 children with the King, beginning with a short-lived daughter in March 1669. She hired a friend of hers, Madame Scarron (later known as Madame de Maintenon) to be the childrens' governess--a bad move, it would turn out, but not for many years. In 1673, her 3 living royal children were given the last name de Bourbon and titles. Louis-Auguste became duc du Maine; Louis-Cesar the comte de Vexin; and Louise-Francois was named Mademoiselle de Nantes (she later married the prince de Conde). They seldom saw their mother, and came to consider Maintenon their true parent. By 1674, she was officially separated from Montespan, but she soon got into trouble of another sort with the notorious Affair of the Poisons.
Before 6 judges at the Chatelet, Athenais was accused of conspiring with the "witch" La Voisin to use black magic to maintain the King's love. (She was also accused of taking part in "black masses", complete with blood sacrifices over her nude body). In another accusation, which would seem to cancel out the first, she was said to conspire to poison the King. (For more info on this complex case, you can look here). Nothing was proved against her, and from 1680 onward her part in the case was hushed up by the King, along with Colbert, Louvois, and Maintenon.
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Some good sources on her life are:
Lisa Hilton, Athenais: The Real Queen of France
Antonia Fraser, Love and Louis XIV
Anne Somerset, The Affair of the Poisons
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